Weathering process at the natural fission reactor of Bangombé     

G. Bracke  S. Salah  F. Gauthier-Lafaye 《Environmental Geology》2001,40(4-5):403-408

 The uranium deposits in the basin of Franceville (Gabon) host the only natural fission reactors known in the world. Unique geological conditions favoured a natural fission reaction 2 Ga ago. This was detected by anomalous isotopic compositions of uranium and rare earth elements (REE), which are produced by the fission reaction. In total, 16 reactor zones were found. Most of them are mined out. The reactor zone of Bangombé, is only 10–11 m below the surface. This site has been influenced by surface weathering processes. Six drill cores have been sampled at the site of the reactor zone of Bangombé during the course of the study and only one drill core (BAX 08) hit the core of the reactor. From these data and previous drilling campaigns, the reactor size is estimated to be 10 cm thick, 2–3 m wide and 4–6 m long. The migration of fission products can be traced by the anomalous isotope ratios of REE because of the fission process. The ¹⁴⁹Sm/¹⁴⁷Sm ratio close to the reactor zone is only 0.28 (normal: 0.92) because of the intense neutron capture of ¹⁴⁹Sm and subsequent transmutation, whereas ¹⁴⁷Sm is enriched by the fission reaction. Similar changes in isotopic patterns are detectable on other REE. The isotope ratios of Sm and Nd of whole rock and fracture samples surrounding the reactor indicate that fission-genic REE migrated only a few decimetres above and mainly below the reactor zone. Organic matter (bitumen) seems to act as a trap for fission-genic REE. Additional REE-patterns show less intense weathering with increasing depth in the log profile and support a simple weathering model. Received: 26 November 1999 · Accepted: 2 May 2000  相似文献   

Crystal chemical significance of chemical zoning in dissakisite-(Ce)     

Mihoko Hoshino  Mitsuyoshi Kimata  Norimasa Nishida  Masahiro Shimizu 《Physics and Chemistry of Minerals》2008,35(2):59-70

Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types. Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F ₀| > 4σF ₀] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal, where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified as autoepitaxy.  相似文献   

四十里湾几种双壳贝类及污损动物的氮、磷排泄及其生态效应   总被引：16，自引：1，他引：16  

周毅  杨红生  何义朝  张福绥 《海洋与湖沼》2002,33(4):424-431

对多种经济双壳贝类和养殖中的污损动物的N和P排泄进行了测定 ,包括排泄成分和排泄速率。在这些动物的N排泄中 ,NH4 N占主要部分 ,如笼式养殖的双壳贝类NH4 N占总N排泄的平均值范围为 70 8%— 80 1 % ;氨基酸是第二大排泄成分 ,平均占总N排泄的 1 0 %—2 5 %。其他形态的N ,如尿素、亚硝酸盐和硝酸盐也有检出。在P排泄中 ,有机磷 (DOP)约占总溶解磷 (TDP)排泄的 1 5 %— 2 7%。据估算 ,整个四十里湾所养殖的双壳贝类在夏季每天将排泄4 5 4t总溶解氮 ,其中NH4 N 3 36t、Amino N 0 69t、Urea N 0 2t。同时每天磷的排泄为 0 5 7tTDP ,其中DOP 0 1 5t。对面积为 1 3× 1 0 4 hm2 的海区而言 ,贝类的N、P排泄分别能满足浮游植物生产所需N、P的 44%和 40 %。高密度的贝类养殖对养殖生态系统营养循环的影响是很显著的。附着动物 (柄海鞘等 )的N、P排泄及其对营养循环的影响也不容忽视。  相似文献   

台湾浅滩西部水域海洋动物的石油烃含量和荧光光谱特征     

贾晓平  林钦  吕晓瑜  宗志伦 《台湾海峡》1990,(3)

本文报道了台湾浅滩西部水域鱼类、虾类和软体头足类动物的总石油烃含量,分析了主3类动物样品的荧光光谱特征,并将本文数据与南海其他水域海洋动物的石油烃含量作了比较。  相似文献   

Effect of marine animal excretions on differential growth of phytoplankton species   总被引：2，自引：0，他引：2  

Arzul  Genevieve; Seguel  Miriam; Clement  Alejandro 《ICES Journal of Marine Science》2001,58(2):386-390

  相似文献   

Assessing the population size of the European storm petrel (Hydrobates pelagicus) using spatial autocorrelation between counts from segments of criss-cross ship transects     

van der Meer  Jaap; Leopold  Mardik F. 《ICES Journal of Marine Science》1995,52(5):809-818

  相似文献   

Monazite behaviour and age significance in poly-metamorphic high-grade terrains: A case study from the western Musgrave Block, central Australia     

Nigel M. Kelly  Geoffrey L. Clarke  Simon L. Harley 《Lithos》2006,88(1-4):100-134

Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.  相似文献   

Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy   总被引：1，自引：0，他引：1  

Riccardo BiddauRosa Cidu  Franco Frau 《Chemical Geology》2002,182(1):1-14

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.  相似文献   

华北地区部分井孔稀有气体异常研究   总被引：2，自引：0，他引：2       下载免费PDF全文

张培仁  刘成龙  王志敏  陶京玲  杨海祥  杨竹转  孟彩菊 《地震地质》2002,24(2):215-222

介绍了近年来华北地区宝龙等 3口井稀有气体的显著异常 ,并据其特征与井孔水位动态的关系 ,对稀有气体异常的成因进行了理论分析与实验研究。结果表明 ,水位下降 10 0mm ,岩层孔隙、裂隙中的气体体积膨胀 0 0 0 90 % (气体体积百分比 ,下同 )左右。由于地下水位大幅度下降 ,岩层孔隙压力减小 ,积聚在岩层孔隙、裂隙中的气体体积膨胀溢出 ,导致井孔地下水中稀有气体含量出现异常变化。这些异常是干扰因素所致 ,不是地震异  相似文献   

大型土壤动物在鞍山市大孤山铁矿废弃地生态环境恢复与重建中的指示作用   总被引：19，自引：0，他引：19  

吴东辉  胡克 《吉林大学学报(地球科学版)》2003,33(2):213-216

对鞍山市大孤山铁矿废弃地大型土壤动物的生态特征进行了调查，分析研究铁矿废弃地自然生态环境的演化和大型土壤动物群落变化的关系，在大孤山铁矿废弃地生态环境恢复与重建中大型土壤动物具有重要的指示作用。大型土壤动物种类、数量变化标志大孤山铁矿废弃地生态环境恢复与重建阶段先后；大型土壤动物群落生态结构与生物量的变化指示铁矿废弃地生态环境恢复与重建质量；蚁科与腹足纲是大孤山铁矿废弃地生态环境恢复与重建的重要指示物种。  相似文献